The Herculoids (1967)

Season 1: Episode 24

Queen Skorra unleashes a mud/lava creature which they eventually defeat, but Skorra plans to force them into exile by sending her drones to capture Gleep, Gloop, Tara, and Dorno. They defend themselves long enough for Zandor and the others to return and drive off the drones. Skorra launches a mega-shield missile and closes the mega-circle to destroy everyone, but Tundro creates a smokescreen while the others make a tunnel to escape and then send Skorra running.