Where on Earth Is Carmen Sandiego? (1994)

Season 2: Episode 3

Zack creates a computer, the Zack Attack 20,000, which he believes will capture Carmen. However, when Carmen escapes with one of the treasures Zack had the computer protect, Ivy decides that she doesn't want to put her faith in it. The siblings go their own separate ways on this case, until Ivy is captured by Carmen.